对称四甲基六元瓜环与银(Ⅰ)配合物的合成与晶体结构 |
Synthesis and Crystal Structure of a Novel Self-assembled 1,4-dimethyl Cucurbituril Silver(Ⅰ) Complex |
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摘要: |
关键词: 对称四甲基六元瓜环 晶体结构 分子胶囊 |
基金项目: |
Abstract: Crystals of a new 1,4-dimethyl cucurbituril(TMeQ[6]) with Silver(Ⅰ) ion were synthesized, and the structure was determined by X-ray diffraction technique. There are two kinds of TMeQ[6] A and B which formed molecular encapsulates with two silver ion lids in the self-assembled entities. One dimensional supramolecular tubes are formed from the encapsulates A, and two dimensional molecular sieves are formed from the encapsulates B, the tubes and the sieves stack together alternately in the self-assembled entities. CCDC: 271401. |
Keywords: 1,4-dimethyl cucurbituril crystal structure molecular encapsulates |
投稿时间:2004-10-25 修订日期:2005-08-04 |
摘要点击次数: 2192 |
全文下载次数: 1908 |
张云黔,陶朱,赵云洁,薛赛凤,祝黔江,魏赞斌,龙腊生.对称四甲基六元瓜环与银(Ⅰ)配合物的合成与晶体结构[J].无机化学学报,2005,21(10):1576-1582. |
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