对称四甲基六元瓜环与银(Ⅰ)配合物的合成与晶体结构
Synthesis and Crystal Structure of a Novel Self-assembled 1,4-dimethyl Cucurbituril Silver(Ⅰ) Complex
作者单位
张云黔 贵州大学应用化学研究所贵阳 550025 
陶朱 贵州大学应用化学研究所贵阳 550025 
赵云洁 贵州大学应用化学研究所贵阳 550025 
薛赛凤 贵州大学应用化学研究所贵阳 550025 
祝黔江 贵州大学应用化学研究所贵阳 550025 
魏赞斌 厦门大学化学系厦门 361005 
龙腊生 厦门大学化学系厦门 361005 
摘要: 
关键词: 对称四甲基六元瓜环  晶体结构  分子胶囊
基金项目: 
Abstract: Crystals of a new 1,4-dimethyl cucurbituril(TMeQ[6]) with Silver(Ⅰ) ion were synthesized, and the structure was determined by X-ray diffraction technique. There are two kinds of TMeQ[6] A and B which formed molecular encapsulates with two silver ion lids in the self-assembled entities. One dimensional supramolecular tubes are formed from the encapsulates A, and two dimensional molecular sieves are formed from the encapsulates B, the tubes and the sieves stack together alternately in the self-assembled entities. CCDC: 271401.
Keywords: 1,4-dimethyl cucurbituril  crystal structure  molecular encapsulates
投稿时间:2004-10-25 修订日期:2005-08-04
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张云黔,陶朱,赵云洁,薛赛凤,祝黔江,魏赞斌,龙腊生.对称四甲基六元瓜环与银(Ⅰ)配合物的合成与晶体结构[J].无机化学学报,2005,21(10):1576-1582.
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