| 新型一维双席夫碱铜(Ⅰ)配合物的合成、结构及荧光性质(英) | |
| Synthesis，Structure and Photoluminescent Property of a Novel 1D Coordination Polymer of Copper(Ⅰ) Complex with Di-Schiff Base Ligand | |
| 摘要: 在室温下，[Cu(PPh3)2(CH3CN)2]ClO4和双席夫碱配体1，2-双(3′-吡啶基亚甲基氨基)乙烷(L)反应得到一个新型化合物[Cu(PPh3)(L)](ClO4) (1)。结构分析表明该化合物属于单斜晶系，空间群为P21 /n，晶胞参数为a=1.696 6(16) | |
| 关键词: 晶体结构 席夫碱配体 铜化合物 荧光性质 | |
| 基金项目: | |
| Abstract: A new coordination polymer [Cu(PPh3)(L)](ClO4) (PPh3=triphenylphosphine) was obtained by reaction of a di-Schiff base ligand 1,2-bis(3′-pyridylmethyleneamino)ethane (L) with [Cu(PPh3)2(CH3CN)2]ClO4. The crystal structure analysis indicates that the complex crystallizes in monoclinic system, space group of P21/n with a=1.696 6(16) nm, b=0.912 4(7) nm, c=1.957 1(18) nm, β=90.797(4)°, V=3.029 7(5) nm3, and Z=4. The structure of [Cu(PPh3)(L)](ClO4) is an infinite zigzag chain in which the copper(Ⅰ) atom has distorted tetrahedral coordination geometry. Photoluminescent property of the complex was investigated. CCDC: 274179. | |
| Keywords: crystal structure schiff base ligand copper(Ⅰ) complex photoluminescent property | |
| 投稿时间：2005-04-25 修订日期：2005-09-12 | |
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| 黄玉婷,欧阳兴梅,岡村高明,李一志,孙为银,上山寭一.新型一维双席夫碱铜(Ⅰ)配合物的合成、结构及荧光性质(英)[J].无机化学学报,2005,21(10):1479-1482. | |
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