| 铜(Ⅱ)、锰(Ⅱ)、镍(Ⅱ)高分子配合物的合成、表征与催化性质研究 |
| Synthesis, Characterization and Catalytic Properties of Cu(Ⅱ), Mn(Ⅱ), Ni(Ⅱ) Dendritic Complexes |
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| 摘要: 合成出以乙二胺为核，马来酸酐为支化结构单元的马来酰胺树枝状高分子、高分子配体及其铜、锰、镍配合物，通过凝胶渗透色谱、红外光谱、紫外光谱、X-射线光电子能谱等对产物进行了结构表征，并就金属配合物对催化分解双氧水反应进行了研究。 |
| 关键词: 树枝状高分子 合成 表征 催化性能 |
| 基金项目: |
| Abstract: Using ethylenediamine as core and maleic anhydride as branched units, a type of dendritic polymers ligand and its copper(Ⅱ), maganese(Ⅱ) and nickel(Ⅱ) complexes have been prepared. The dendrimers were characterized by Gel Permeation Chromatography, IR, UV and XPS spectroscopy. The catalysis of dendritic complexes for decomposition of hydrogen peroxide was also studied. |
| Keywords: dendritic polymers synthesis characterization catalytic rroperties |
| 投稿时间：2005-03-06 修订日期：2005-05-30 |
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| 高丰琴,王博,马红竹,闫小宁.铜(Ⅱ)、锰(Ⅱ)、镍(Ⅱ)高分子配合物的合成、表征与催化性质研究[J].无机化学学报,2005,21(10):1460-1464. |
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