含轴手性磺酸配体的镉配合物(英) |
Cd(Ⅱ) Complex with Disulfonate Atropisomeric Ligand |
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摘要: |
关键词: 晶体结构 6,6′-二溴-2,2′-二甲氧基-1,1′-二萘-4,4′-二磺酸 镉 |
基金项目: |
Abstract: The crystal structure of [Cd(BDA)(phen)2(H2O)](H2O)2 (1) (BDA=6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene-4,4′-disulfonate, phen=1,10-phenanthroline)consists of a cadmium center whose coordination environment can be best described as a slightly distorted octahedron defined four nitrogen atoms from two phen ligands and two oxygen atoms differently from BDA ligand and water. There are strong hydrogen-bonding interactions between water and sulfonate group of BDA ligands to construct the 3D network. CCDC: 277921. |
Keywords: crystal structure 6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene-4,4 ′-disulfonic acid cadmium |
投稿时间:2005-02-15 修订日期:2005-06-01 |
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唐云志,周挺.含轴手性磺酸配体的镉配合物(英)[J].无机化学学报,2005,21(9):1435-1436. |
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