| 对甲苯磺酰甘氨酸构建的鼓型有机锡簇合物的合成与晶体结构(英) | |
| Synthesis and Crystal Structure of a Drum Organooxotin Cluster Constructed from N-p-tolysulfonyl-glycine | |
| 摘要: | |
| 关键词: 有机锡簇合物 对甲苯磺酰甘氨酸 晶体结构 | |
| 基金项目: | |
| Abstract: The title complex [ nBuSn(O)(tsglyO)]6·6CHCl3 (tsglyO=N-p-tolysulfonyl-glycinate monoanion) was synthesized by the reaction of nBuSn(O)OH with N-p-tolysulfonyl-glycine in 1∶1 molar ratio. The complex was characterized by IR, 1H NMR spectra and elemental analysis. The crystal structure was determined by X-ray diffraction method. It crystallizes in rhombohedral system with space group R3. The crystal data are: a=b=2.738 7(4) nm, c=1.446 5(4) nm, α=β=90°, γ=120°, Z=6, Dc=1.726 g·cm-3, F(000)=4 878, V=9.396(3) nm3, R1=0.032 5, wR2=0.089 8. The structure shows a distorted octahedral configuration with six-coordination for the central tin atom. CCDC: 274183. | |
| Keywords: organooxotin cluster N-p-tolysulfonyl-glycine crystal structure | |
| 投稿时间：2005-01-07 修订日期：2005-05-12 | |
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| 张春华,陈满生,邝代治,邓奕芳,陈志敏,余润兰,杨颖群.对甲苯磺酰甘氨酸构建的鼓型有机锡簇合物的合成与晶体结构(英)[J].无机化学学报,2005,21(9):1386-1388. | |
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