层状正极材料LiNi1/6Co1/6Mn2/3O2的制备及电池性能
Preparation of Positive Material LiNi1/6Co1/6Mn2/3O2 for Li Ion Battery
作者单位
陈丽 天津大学理学院化学系天津 300072 
田宜灵 天津大学理学院化学系天津 300072 
杨俊 天津大学理学院化学系天津 300072 
贾东镇 天津大学理学院化学系天津 300072 
摘要: 
关键词: LiNi1/6Co1/6Mn2/3O2  固-液相合成法  比容量  充放电效率  循环性能
基金项目: 
Abstract: A positive material LiNi1/6Co1/6Mn2/3O2 has been prepared by using solid-liquid phase method. A layer structure similar to LiMnO2 was shown by XRD analysis. The positive electrode of the material had a higher specific capacity, and the reversible specific capacity and irreversible capacity increased with the increase of charge cut-off voltage which has the optimum value of 4.4 V. The battery using the material had higher initial charge-discharge efficiency and better high rate discharge performance, and the cyclic life had also been improved obviously. At the same time, the battery was with excellent high and low temperature performance, and safe performance.
Keywords: LiNi1/6Co1/6Mn2/3O2  solid-liquid phase synthesis method  specific capacity  charge-discharge efficiency  cyclic life
投稿时间:2004-12-20 修订日期:2005-05-08
摘要点击次数:  1305
全文下载次数:  1750
陈丽,田宜灵,杨俊,贾东镇.层状正极材料LiNi1/6Co1/6Mn2/3O2的制备及电池性能[J].无机化学学报,2005,21(7):1105-1108.
查看全文  查看/发表评论  下载PDF阅读器
Support information: