| 5-取代-1-氢四唑合成中捕获的一个新奇的三维镉配聚物(英) |
| An Unexpected Intermediate or Precipitate——Novel 3D Cd-Coordination Polymer Formed in the Preparation of 5-Substituted 1H-Tetrazoles from Nitrile in Water |
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| 摘要: 在水热条件下，1，4-对二氰基苯，氯化镉以及叠氮化纳反应,成功地组装了一个三维网状镉四唑配位聚合物[monoaqua-4-tetrazolyl-benzenecarboxylate cadmium(Ⅱ)(1)],该化合物并不是预期的双四唑镉配位聚合物，而是其中一个氰基水解成羧基形成了单四唑镉配位聚合物。晶体结构分析表明，化合物1具有PtS的拓扑结构，室温下，化合物1显示强的蓝色荧光。 |
| 关键词: 镉 水热合成 配位聚合物 荧光 |
| 基金项目: |
| Abstract: The hydrothermal reaction of 1,4-dicyanobenzene with NaN3 in the presence of H2O and Lewis acid (CdCl2) unexpectedly affords a novel mono-tetrazole Cd coordination polymer, monoaqua-4-tetrazolyl-benzenecarboxylate cadmium(Ⅱ) (Te-Ph-CA)Cd(H2O) (1) , rather than an expected Sharpless′s precipitate product with bis(tetrazolyl)benzene ligand. 3D Network of 1 with a PtS topology highlights the importance in construction novel supramolecular motifs through in situ ligand-synthesis. Its strong blue fluorescent property is also reported. CCDC: 215388. |
| Keywords: Cd hydrothermal reaction coordination polymer fluorescent |
| 投稿时间：2005-04-01 修订日期：2005-05-31 |
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| 王锡森,黄雪峰,熊仁根.5-取代-1-氢四唑合成中捕获的一个新奇的三维镉配聚物(英)[J].无机化学学报,2005,21(7):1020-1024. |
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