| 呋喃甲醛缩二乙撑三胺希夫碱铜配合物的合成及结构(英) |
| Synthesis and Structure of a New Copper(Ⅱ) Complex with Schiff Base Derived from Furaldehyde and Diethylenetriamine |
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| 摘要: |
| 关键词: 呋喃甲醛 希夫碱 铜配合物 晶体结构 |
| 基金项目: |
| Abstract: A novel copper(Ⅱ) complex CuL(NO3)2(where L=N,N′-bis(furaldehyde)-diethylenetriamine) was synthesized and characterized by X-ray crystallography analysis. The crystal belongs to monoclinic, space group C2/c with cell parameters a=1.924 0(6) nm, b=0.792 8(3) nm, c=2.504 1(8) nm, β=111.163(5)°, and Z=8. The coordination geometry around Cu(Ⅱ) is a distorted trigonal-bipyramid，and one-dimensional chain is formed through intermolecular hydrogen bonds. CCDC: 255629. |
| Keywords: furaldehyde Schiff base copper(Ⅱ) complex crystal structure |
| 投稿时间：2004-11-15 修订日期：2005-01-13 |
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| 杜桂香,王伟,李珺,张逢星.呋喃甲醛缩二乙撑三胺希夫碱铜配合物的合成及结构(英)[J].无机化学学报,2005,21(6):938-940. |
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