一个二核钒配合物的合成及晶体结构:NH4[(VⅣO)2(μ2-O)(nta)2][EuⅢ(H2O)9](英) | |
Synthesis and Crystal Structure of a Binuclear Vanadium Complex: NH4[(VⅣO)2(μ2-O)(nta)2][EuⅢ(H2O)9] | |
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关键词: 氮三乙酸 钒 合成和晶体结构 | |
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Abstract: A binuclear vanadium complex NH4[(VⅣO)2(μ2-O)(nta)2][EuⅢ(H2O)9] was synthesized by reaction of NH3VO3, nitrilotriacetic acid and EuCl3 in one aqueous solution. The crystal X-ray analysis shows that the complex contains one binuclear vanadium anion [(VⅣO)2(μ2-O)(nta)2]4- and one [EuⅢ(H2O)9]3+ cation. The molecules are built up to a three-dimensional supramolecular structure through hydrogen bonding. CCDC: 238716. | |
Keywords: nitrilotriacetic acid vanadium synthesis and crystal structure | |
投稿时间:2004-04-26 修订日期:2004-08-27 | |
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张全争,陈淑妹,余雅琴,何翔,闫莹,刘九辉,许新江,夏昌坤,陈丽娟,吴小园,卢灿忠.一个二核钒配合物的合成及晶体结构:NH4[(VⅣO)2(μ2-O)(nta)2][EuⅢ(H2O)9](英)[J].无机化学学报,2005,21(1):101-104. | |
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