| N-邻羟苄亚基苯胺Schiff碱铜配合物的合成、结构和性能表征(英) |
| Synthesis, Structure and Properties of Copper(Ⅱ) Complex with Schiff Base Ligand N-Salicylidene-aniline: [Cu(C13H10NO)2] |
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| 摘要: |
| 关键词: Schiff碱 铜配合物 TG 晶体结构 |
| 基金项目: |
| Abstract: The structure of the title compound has been determined by X-ray crystallography. Each copper atom is chelated by two N-salicylidene-aniline anion ligands with Cu-O and Cu-N distances of 0.187 6(3) and 0.200 1(4) nm, respectively. The central copper(Ⅱ) is four-coordinated and in distorted square-planar environment. The phenyl rings with salicylidene moieties form a dihedral angle of 65.40°. There are C-H…π supramolecular interactions in the crystal structure. The title compound is also examined by elemental analysis, FT-IR, UV spectra and TG-DSC analysis. CCDC: 222315. |
| Keywords: Schiff base copper(Ⅱ) complex TG crystal structure |
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| 建方方,李 琳,孙萍萍,肖海连.N-邻羟苄亚基苯胺Schiff碱铜配合物的合成、结构和性能表征(英)[J].无机化学学报,2004,20(11):1295-1298. |
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