| 一个新颖的二茂铁羧酸混配合物的制备、晶体结构及电化学性质研究 |
| Synthesis, Crystal Structure and Electrochemical Character of a Novel Mixed-ligand Complex from Ferrocene Carboxylates |
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| 摘要: 本文以3-二茂铁羰基丙酸(L1)、1，1′-二茂铁二羰基-3，3′-双丙酸(L2)、2，2′-联吡啶胺(dpa)以及Zn(Ac)2·2H2O为原料合成了一个结构新颖的混配合物[Zn2(L1)2(L2)(dpa)]。X-射线单晶衍射分析表明，该配合物是一个中心对称的双核配合物，并在N-H…O氢键和C-H…O氢键的作用下形成了二维的超分子化合物。采用差示脉冲对该配合物的电化学性质进行了初步的研究。 |
| 关键词: 二茂铁羧酸 混配合物 晶体结构 差示脉冲 |
| 基金项目: |
| Abstract: A novel mixed-ligand complex [Zn2(L1)2(L2)(dpa)] (L1=3-ferrocenoylpropionic acid, L2=1,1′-ferrocenedipropionic acid, dpa=2,2′-dipyridylamine) has been synthesized by the reaction of Zn(Ac)2·2H2O with L1, L2 and dpa and characterized by X-ray single crystal diffraction. The results reveal that it is a centrosymmetric binuclear complex. The hydrogen bonds N-H…O and C-H…O connect [Zn2(L1)2(L2)(dpa)] units into a supramolecular of 2-D structure. In addition, the electrochemical character of the complex was investigated by differential pulse volt-metric techniques. CCDC: 247065. |
| Keywords: ferrocene carboxylate mixed-ligand complex crystal structure electrochemical character |
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| 陈茜茹,徐 虹,侯红卫.一个新颖的二茂铁羧酸混配合物的制备、晶体结构及电化学性质研究[J].无机化学学报,2004,20(10):1155-1158. |
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