| 配位聚合物[HgI2(btx)]n的制备、晶体结构及性能研究(btx=对二(1，2，4-三氮唑基甲基)苯) |
| Synthesis, Crystal Structure and Properties of the Coordination Polymer [HgI2(btx)]n (btx=1-[4-(1H-1,2,4-triazol-1-ylmethyl)benzyl]-1H-1,2,4-triazole) |
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| 摘要: |
| 关键词: 配位聚合物 晶体结构 差热及热重分析 荧光性质 |
| 基金项目: |
| Abstract: A novel one-dimension coordination polymer [HgI2(btx)]n was synthesized through the reaction of alpha, alpha’-dichloro-p-xylene and HgI2 in mixed MeOH-THF (1∶1) solution. The compound was characterized by X-ray crystallography and crystallizes in orthorhombic with space group Pnma. The cell parameters of the title compound are: a=0.936 3(2) nm, b=1.769 4(4) nm, c=1.032 2(2) nm, α=90°. Attractive I…I interactions link HgI2(btx) chains directly resulting in the formation of three-dimensional network structure. In addition, the compound shows better luminescence spectroscopic property in the solid state, and is thermally stable below 126 ℃. CCDC: 233053. |
| Keywords: coordination polymer crystal structure thermal analysis luminescence spectroscopic property |
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| 徐 虹,孟祥茹,韩华云,王 霞,侯红卫.配位聚合物[HgI2(btx)]n的制备、晶体结构及性能研究(btx=对二(1，2，4-三氮唑基甲基)苯)[J].无机化学学报,2004,20(9):1089-1092. |
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