| 超分子自组装合成杯[4]芳烃黄原酸镍(Ⅱ)配合物 |
| Supramolecular Self-assembled Calix[4]arene Xanthate-Ni2+ Complex Compound |
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| 摘要: |
| 关键词: 杯[4]芳烃 黄原酸盐 自组装 镍配合物 |
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| Abstract: Under the action of CS2 and KOH in dioxane solution, calix[4]arene derivative 2 was converted into calix[4]arene derivative containing xanthate salt (3) and its Ni2+ complex compound 4 was prepared by self-assembled reaction with NiSO4 further. The structures of new compounds were confirmed by elemental analyses, IR, UV, 1H NMR, MS techniques. The Ni2+ of complex compound 4 was in high-spin state by its ESR spectrum. |
| Keywords: calix[4]arene xanthate self-assembled Ni2+ complex |
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| 杨发福,陈希磊,蔡秀琴,林 深,陈远荫.超分子自组装合成杯[4]芳烃黄原酸镍(Ⅱ)配合物[J].无机化学学报,2004,20(9):1081-1084. |
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