叠氮和1-(4-吡啶基)-2-(2-苯甲氰基)乙烯锌(Ⅱ)配合物的合成与晶体结构(英) |
The Synthesis and Crystal Structure of a Zn(Ⅱ) Complex with Azide and 1-(4-Pyridyl)-2-(2-cyanobenzene) Ethylene |
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摘要: |
关键词: 叠氮 锌配合物 晶体结构 |
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Abstract: The hydrothermal reaction of Zn(NO3)2, NaN3, and 1-(4-pyridyl)-2-(2-cyanobenzene) ethylene (PCE), at the mole ratio 1∶2∶2 in methanol and water at 70 ℃ for two days afforded [Zn(PCE)2(N3)2], the structure of which features a four-coordinated distorted tetrahedron geometry around zinc(Ⅱ). CCDC: 235945. |
Keywords: azide zinc complex crystal structure |
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谢永荣,唐云志,熊仁根.叠氮和1-(4-吡啶基)-2-(2-苯甲氰基)乙烯锌(Ⅱ)配合物的合成与晶体结构(英)[J].无机化学学报,2004,20(8):1005-1006. |
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