1,10-邻啡啰啉取代的希夫碱配体及其双核配合物的合成(英)
Synthesis of a Phenanthroline Substituted Schiff Base Ligand and Its Binuclear Complexes
作者单位
陈宏基 暨南大学化学系广州 510632 
摘要: 
关键词: 1,10-邻啡啰啉5,6-双(水扬醛)亚氨 希夫碱 双核配合物
基金项目: 
Abstract: A new ligand N, N′-Bis(salicyidene)-5,6-phenanthrolinenediamine (H2L) 1 and its four binuclear complexes [M2+LM2+(B-)2]( M=Cu2+, B-=Ac-, 1a; M=Ni2+, B-=Ac-, 1b; M=Co2+, B-=Cl-, 1c; M=Ni2+, B-=Cl-, 1d) have been prepared by condensing 1 equiv. of 5,6-diamino-1,10-Phenanthroline with 2 equiv. of 2-hydroxybenzaldehyde and reaction of 1 with metal salts, and characterized by IR, 1H and 13C NMR, UV-Vis and EI-MS analysis.
Keywords: N,N′-Bis(salicyidene)-5,6-phenanthrolinenediamine Schiff base binuclear complex
 
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陈宏基.1,10-邻啡啰啉取代的希夫碱配体及其双核配合物的合成(英)[J].无机化学学报,2004,20(8):1001-1004.
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