| 一个新的钴磷酸盐配合物Co(μ3-O3P)·H2O的合成与晶体结构 |
| Synthesis and Crystal Structure of a Novel Cobalt Phosphate Complex Co( μ3-O3P)·H2O |
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| 摘要: |
| 关键词: 钴磷酸盐 配合物 晶体结构 |
| 基金项目: |
| Abstract: A new layered cobalt phosphate complex, Co( μ3-O3P)·H2O, was prepared by the hydrothermal reaction. The crystal structure of the complex was determined by single-crystal X-ray diffraction. The results indicate that it contains two different infinite PO3chains linked by CoO6 octahedra with infinite 1-D tunnels. It crystallizes in the orthorhombic space group Pbcm with a=0.790 12(16) nm, b=0.900 25(18) nm, c=1.016 1(2) nm, β=90°, V=1.245 3nm3, Z=4. Refinement gave R1=0.068 5, wR2=0.175 1 for 2 133 unique observed reflections (I>2σ(I)). The title complex was also characterized by IR, TG-DTA and chemical analysis. CSD: 413934. |
| Keywords: cobalt phosphate complex crystal structure |
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| 杜晨霞,薛东旭,程小宁,樊耀亭,侯红卫,卢会杰.一个新的钴磷酸盐配合物Co(μ3-O3P)·H2O的合成与晶体结构[J].无机化学学报,2004,20(8):955-958. |
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