| 由三核铁构筑成的新型的二维网状超分子化合物的合成、结构与性质(英) |
| Synthesis, Structure and Magnetic Properties of a Novel 2-D Supramolecular Network Formed by the Fe3O Building Unit through Three Hydrogen Bonds |
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| 摘要: |
| 关键词: 二维网状超分子 Fe3O 氢键 |
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| Abstract: A novel 2-D supramolecular network formed by the Fe3O building unit through three hydrogen bonds [Fe3O(O2CCH2OC6H5)6(3H2O)]NO3·2H2O (1) are presented. The title complex crystallizes in monoclinic, space group P21/n, with a=1.709 3(2) nm, b=3.152 9(3) nm, c=1.021 2(2) nm, V=5.5035(14) nm3, Z=4, D(calc)=1.500 g·cm-3, F(000)=2 564. Each Fe3O unit is connected by three NO3- ions and inversely each NO3- ion is surrounded by three Fe3O moieties. It shows that the well-known Fe3O unit is a potential three H-donors and may be able to be a three-connected linker. This complex displays weak anti-ferromagnetic coupling between Fe(Ⅲ) centers. Electrochemical experiments were carried out to obtain the character of its redox reaction. CCDC: 222011. |
| Keywords: 2-D supramolecular network Fe3O H-bonding |
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| 杨玉华,李一志,韦吉崇,游效曾,王天维,白俊峰.由三核铁构筑成的新型的二维网状超分子化合物的合成、结构与性质(英)[J].无机化学学报,2004,20(6):683-687. |
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