铜配位聚合物[Cu(C5H6S5)(SCN)]∞的合成和结构研究(英) |
Synthesis and Crystal Structure of a Copper(Ⅰ) Coordination Polymer with 4,5-bis(methylthio)-1,3-dithiole-2-thione Ligand |
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摘要: |
关键词: 铜配合物 晶体结构 配位聚合物 超分子 多硫配合物 |
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Abstract: The Copper(Ⅰ) supramolecular complexes of 4,5-bis(methylthio)-1,3-dithiole-2-thione (C5H6S5), [Cu(C5H6S5)(SCN)]∞ 1 and [Cu(C5H6S5)I]∞ 2, have been prepared and characterized. X-ray structure analysis for complex 1 reveals that the infinite chain structure with polymeric stairs of different lengths is formed through the coordination mode (μ3) of the thiocyanate bridges. The shorter interchain S…S contacts give rise to a three-dimensional network structure. CCDC: 215668. |
Keywords: copper complexes crystal structures polymeric complexes supramolecular complexes thione complexes |
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方国苏,纪 勇,王 石,左景林,白俊峰,游效曾.铜配位聚合物[Cu(C5H6S5)(SCN)]∞的合成和结构研究(英)[J].无机化学学报,2004,20(5):603-607. |
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