| 网络骨架组装工程：5-硝基间苯二甲酸形成的配位聚合物网络多样性 |
| Framework Assembly Engineering: Network Diversity of Coordination Polymers Constructed by 5-Nitroisophthalic Acid |
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| 摘要: |
| 关键词: 配位聚合物 5-硝基间苯二甲酸 晶体结构 骨架工程 组装 |
| 基金项目: |
| Abstract: Two novel coordination polymers, [Cu(nip)(phen)]n (1) and [Co2(nip)2(phen)2]n (2), have been synthesized by hydrothermal synthesis using 5-nitroisophthalic acid (H2nip), 1,10-phenanthroline (phen) and metal salts and structurally characterized by X-ray single-crystal structure analysis. The results indicated that the nip ligand in compound 1 has a μ3 mono-atomic bridging-monodentate coordination mode and the structure is a two-dimensional network, while the nip ligand in compound 2 has a chelating-bridging coordination mode and the structure is a one-dimensional network. CCDC: 222202, 1; 222203, 2. |
| Keywords: coordination polymer 5-nitroisophthalic acid crystal structure framework engineering assembly |
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| 周以力,何洪银,朱龙观.网络骨架组装工程：5-硝基间苯二甲酸形成的配位聚合物网络多样性[J].无机化学学报,2004,20(5):576-580. |
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