| 一维链状超分子化合物[Zn(dafo)2(H2O)2](NO3)2(dafo=4，5-二氮芴-9-酮)的合成、表征和晶体结构 |
| Preparation, Characterization and Crystal Structure and of a One-dimensional Chain Supramolecular Compound [Zn(dafo)2(H2O)2](NO3)2 (dafo=4,5-Diazafluorene-9-one) |
|
| 摘要: |
| 关键词: 4，5-二氮芴-9-酮 超分子化合物 Zn(Ⅱ)配合物 晶体结构 |
| 基金项目: |
| Abstract: A novel one-dimensional chain complex [Zn(dafo)2(H2O)2](NO3)2 was synthesized. It has been characterized by IR, UV, TGA, Elemental analysis and X-ray diffraction analysis. The crystal belongs to triclinic system, P1 space group. The Crystallographic data are: a= 0.702 7(14) nm, b= 0.828 95(17) nm, c= 10.225(2) nm, α = 95.02(3)°, β = 91.45(3)°, γ = 99.85(3)°. The crystal structure data indicate that the Zn(Ⅱ) ion was coordinated with the four nitrogen atoms of two dafo and two oxygen atoms of two coordination water molecules, respectively. The complex has a one-dimensional chain structure, which is formed by hydrogen bonds. |
| Keywords: 4,5-Diazafluorene-9-one (dafo) supramolecule compound Zn(Ⅱ) complex crystal structure |
| |
| 摘要点击次数: 1295 |
| 全文下载次数: 1592 |
| 徐 晨,毛红艳,张鸿云,刘红磊,吴庆安,侯红卫,朱 玉.一维链状超分子化合物[Zn(dafo)2(H2O)2](NO3)2(dafo=4，5-二氮芴-9-酮)的合成、表征和晶体结构[J].无机化学学报,2004,20(5):539-542. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
