| 新颖一维配位聚合物[Ni(3，5-pdc)(H2O)4]·(H2O)的合成与晶体结构 |
| Synthesis and Crystal Structure of a Novel One-Dimensional Coordination Polymer, [Ni(3,5-pdc)(H2O)4]·(H2O) |
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| 摘要: |
| 关键词: 3,5-吡啶二甲酸 镍 配位聚合物 晶体结构 |
| 基金项目: |
| Abstract: The hydrothermal reaction of 3,5-pyridinedicarboxylic acid and NiCl2·6H2O results in a novel coordination polymer， [Ni(3,5-pdc)(H2O)4]·(H2O). The crystal structure of the compound was determined by X-ray single crystal diffraction. The crystal belongs to monoclinic system with space group P21/n, a=1.136 1(3)nm, b=0.709 8(2) nm, c=1.459 7(4) nm, β=107.538(4)°， V=1.122 4(6) nm3, Dc=1.858 g·cm-1, Z=4, F(000)=648, R1=0.0264, wR2=0.0665. CCDC: 224880. |
| Keywords: 3,5-pyridinedicarboxylic acid Ni coordination polymer crystal structure |
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| 李春辉,司书峰,王如骥,李亚栋.新颖一维配位聚合物[Ni(3，5-pdc)(H2O)4]·(H2O)的合成与晶体结构[J].无机化学学报,2004,20(5):536-538. |
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