| Abstract: The tri(o-bromobenzyl)tin bromide was treated with aqueous solution of NaOH to formed the μ-oxygen-bis[tri(o-bromobenzyl)tin]. The crystal structures of compound was determined by X-ray diffraction. The crystal belongs to triclinic, space group with a=1.0544(4) nm, b=1.1029 (4) nm, c=1.1309 (4) nm, α =117.031(5) °, β=107.685 (6) °, γ=98.523(6) °, V=1.0506(6)nm3, Z=1, Dx=2.013g·cm-3, μ(MoKα)=69.25cm-1, F(000)=606, R1=0.0524, wR2=0.1196. In the struture the tin atom has a distorted tetrahedral geometry. CCDC: 220514. |
