| 混合配体配合物钯(Ⅱ)-联喹啉-苯乙基丙二酸根与DNA作用研究 |
| Study on the Interaction of Mixed Ligand Complex Palladium(Ⅱ)-biquinoline-phenethylmalonate with DNA |
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| 摘要: |
| 关键词: 钯(Ⅱ) 联喹啉 苯乙基丙二酸 配合物 DNA |
| 基金项目: |
| Abstract: The mixed ligand complex [Pd(biqu)(pmal)]·H2O (where biqu is 2,2′-biquinoline, pmal is phenethylmalonate) has been synthesized and its interaction with sperm DNA was determined by fluorescent spectra、 UV-Vis spectra and CD-spectra. The binding constant (Kb) of the complex and sperm DNA is 1.26×104 and its interaction with pBR322 plasmid DNA was also determined by gel electrophoresis. The results show that the complex interact with DNA mainly by intercalative mode. |
| Keywords: palladium(Ⅱ) biquinoline phenethylmalonate complex DNA |
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| 高恩君,赵淑敏,刘祁涛.混合配体配合物钯(Ⅱ)-联喹啉-苯乙基丙二酸根与DNA作用研究[J].无机化学学报,2004,20(2):191-194. |
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