铟硼磷酸盐结构中的交叠生长规律研究(英)
Studies on the Intergrowth Structures in Indium (In) Borophosphates
作者单位
毛少瑜 厦门大学化学化工学院,厦门 361005 
李满荣 高性能陶瓷和超微结构国家重点实验室,中国科学院上海硅酸盐研究所,上海 200050
厦门大学化学化工学院,厦门 361005 
魏赞斌 厦门大学化学化工学院,厦门 361005 
宓锦校 厦门大学化学化工学院,厦门 361005 
赵景泰 高性能陶瓷和超微结构国家重点实验室,中国科学院上海硅酸盐研究所,上海 200050 
摘要: 
关键词: 交叠生长结构 硼磷酸盐 水热合成 铟
基金项目: 
Abstract: Several indium borophosphates have been reported recently, including KIn[BP(OH)]() and NaIn[BP(OH)](). The latter two compounds were synthesized under mild hydrothermal conditions, and have the same molar ratio (M∶In∶B∶P∶O∶H) in molecular formula but with different structure types. Compound crystallizes in the triclinic system with space group P1 (No.2), =0.52638(4) nm, =0.84791(5) nm, =0.81469(9) nm, α=91.1741(7) °, β=93.061(7) °, γ=79.823(5) °, =0.3573 nm, =2; while compound possesses a monoclinic structure with space group (No.14) with =0.5177(1) nm, =1.6815(3) nm, =0.7684(2) nm, β=94.10(3) °, =0.6672(2) nm, =4. Eight-membered-ring and six-membered-ring are formed by alternating borate, phosphate tetrahedra and In-coordination octahedron sharing corners via common oxygen atoms in compound and respectively. The polyhedra in the structure are oriented along certain direction to form alternating layered fragments. These two structure types can be considered as intergrowth structures, which consist of the same layered fragments growing in different orientations. Other structure intergrowth possibilities are also expected in similar systems. CSD: , 409583; , 413343.
Keywords: intergrowth structure borophosphate hydrothermal synthesis indium
 
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毛少瑜,李满荣,魏赞斌,宓锦校,赵景泰.铟硼磷酸盐结构中的交叠生长规律研究(英)[J].无机化学学报,2004,20(1):53-56.
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