| [Cu(TOL)4]Cl2·2C2H5OH·2H2O的合成和晶体结构 |
| Synthesis and Crystal Structure of [Cu(TOL)4]Cl2·2C2H5OH·2H2O |
| 作者 | 单位 | E-mail | | 张培志 | 浙江科技学院生物与化学工程学系, 杭州, 310012 | zhangpzpz@sohu.com | | 吴军 | 浙江大学化学系, 杭州, 310027 | | | 龚钰秋 | 浙江大学化学系, 杭州, 310027 | | | 胡秀荣 | 浙江大学分析测试中心, 杭州, 310028 | | | 顾建明 | 浙江大学分析测试中心, 杭州, 310028 | |
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| 摘要: 三唑醇(Triadimenol,简写TOL)是一内吸性的广谱低毒杀菌剂,主要用于禾谷类作物,腥黑穗病、丝黑穗病、散黑穗病、白粉病、锈病等病害的防治. |
| 关键词: 三唑醇 铜(Ⅱ)配合物 合成 晶体结构 |
| 基金项目: 浙江省自然科学基金(No.201004);浙江省教育厅基金(No.20010436)资助项目 |
| Abstract: The complex of triadimenol(TOL) and copper chloride was synthesized in ethanol, and its crystal structure had been determined using single crystal X-ray diffraction. The crystal belongs to triclinic, space group P1, a=0.9861(2)nm, b=1.1930(2)nm, c=1.7140(3)nm, α=71.53(3)°, β=81.94(3)°, γ=75.56(3)°, V=1.848(6)nm3, Z=1, Dc=1.295g·cm-3, F(000)=755, R1=0.0692, wR2=0.1845. The results show that the coordination geometry around copper(Ⅱ) in the complex is slightly distorted four coordinated square planar geometry. The title complex was also characterized by elementary analysis, IR and TG. |
| Keywords: triadimenol Cu(Ⅱ) complex synthesis crystal structure |
| 投稿时间：2003-04-08 修订日期：2003-06-02 |
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| 张培志,吴军,龚钰秋,胡秀荣,顾建明.[Cu(TOL)4]Cl2·2C2H5OH·2H2O的合成和晶体结构[J].无机化学学报,2003,19(8):909-912. |
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