| [K2(TNR)(H2O)]n的制备、分子结构和热分解机理 |
| Preparation, Molecular Structure and Thermal Decomposition Mechanism of [K2(TNR)(H2O)]n |
| 作者 | 单位 | E-mail | | 李玉锋 | 北京理工大学机电工程学院, 北京, 100081 | | | 张同来 | 北京理工大学机电工程学院, 北京, 100081 | ztlbit@public.bta.net.cn | | 张建国 | 北京理工大学机电工程学院, 北京, 100081 | | | 马桂霞 | 北京理工大学机电工程学院, 北京, 100081 | | | 宋江闯 | 北京理工大学机电工程学院, 北京, 100081 | | | 孙远华 | 北京理工大学机电工程学院, 北京, 100081 | | | 郁开北 | 中国科学院成都分院分析测试中心, 成都, 610041 | |
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| 摘要: 2,4,6-三硝基间苯二酚(斯蒂芬酸)及其盐类,如斯蒂芬酸铅、斯蒂芬酸钡等是常用的含能材料,但斯蒂芬酸铅盐及钡盐在爆炸后产生重金属污染,对使用人员的健康及环境都产生危害. |
| 关键词: 2,4,6-三硝基间苯二酚 钾配合物 分子结构 热分解机理 |
| 基金项目: |
| Abstract: The new complex, [K2(TNR)(H2O)]n, was prepared by reacting 2,4,6-trinitroresorcinol with potassium hyd roxide. Its crystal structure was determined by X-ray single crystal diffraction analysis. The crystalline belongs to triclinic with space group P1.Its unit cell parameters are as follows:a=0.6993(1)nm, b=0.9474(2)nm, c=0.9791(1)nm, α=115.28(1)°, β=107.86(1)°, γ=95.94(1)°, V=0.53717(15)nm3, Z=2, Dc=2.098g·cm-3, F(000)=340. The two potassium ions have different coordination numbers of which are 8 and 9, respectively. The thermal decomposition mechanism of the complex was studied by using DSC, TG GTG and FT-IR techniques. The existence of KNC in the residue is shown in FT-IR. |
| Keywords: 2,4,6-trinitroresorcinate potassium complex molecular structure thermal decomposition mechanism |
| 投稿时间：2003-01-02 修订日期：2003-03-15 |
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| 李玉锋,张同来,张建国,马桂霞,宋江闯,孙远华,郁开北.[K2(TNR)(H2O)]n的制备、分子结构和热分解机理[J].无机化学学报,2003,19(8):861-864. |
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