分叉碳纳米管的催化生长 |
Catalytic Growth of Branching Carbon Nanotubes |
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摘要: |
关键词: 分叉 碳纳米管 化学气相沉积 催化生长 |
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Abstract: Branching carbon nanotubes were synthesized by pyrolysis of acetylene at 700℃ over oxygen-free copper and γ-Al2O3-supported Cu unitary or Cu/Fe binary catalysts. The morphologies of the as-grown products were charac-terized by transmission electron microscopy. The results indicated that the branching structures were closely related to the Cu component of the catalysts. We proposed that the special electronic structure (3d104s1) of Cu play the crucial role in the formation of the heptagon defects related to the branching structures. |
Keywords: branching carbon nanotubes chemical vapor deposition catalytic growth |
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杨 勇,胡 征,陈 懿.分叉碳纳米管的催化生长[J].无机化学学报,2003,19(7):771-773. |
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