| 具有S…S、S…Cl作用的一维链状有机锡化合物氯代二苄基锡哌啶荒酸酯的合成、表征及晶体结构(英文) |
| Synthesis， Characterization and Crystal Structure of the S…S and S…Cl Interaction One-Dimensional Chain Complex Chlorodibenzyltin Dithiopiperidylcarbamate |
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| 摘要: |
| 关键词: 二苄基锡衍生物 哌啶荒酸 合成 晶体结构 |
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| Abstract: The chlorodibenzyltin dithiopiperidylcarbamate was synthesized by the reaction of dibenzyltin dichloride with dithiopiperidylcarbamate and was characterized by elemental analysis， IR and 1H NMR. The crystal structure was determined by X-ray single crystal diffraction. The crystallographic data are as follows： monoclinic， space group P21， a=0.63464(13)nm， b=1.9110(4)nm， c=0.87367(17)nm， β=97.67(3)°， Z=2， V=1.0501(4)nm3，Dc=1.571g·cm-3， μ=1.546mm-1， F(000)=500， R=0.0209， wR=0.0381 [I≥ 2σ(I)]. The str- uctures consist of discrete molecules containing five-coordinate tin atoms in a seriously distorted trigonal bipyramidal configuration. The molecules are packed in the unit cell in one-dimensional chain complex through a weak inter-action between the chlorine atom， the sulfur atom and one of the other sulfurs of an adjacent molecule. CCDC： 180034. |
| Keywords: denzyltin derivative dithiopiperidylcarbamate synthesis crystal structure |
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| 尹汉东,王传华,马春林,王勇.具有S…S、S…Cl作用的一维链状有机锡化合物氯代二苄基锡哌啶荒酸酯的合成、表征及晶体结构(英文)[J].无机化学学报,2003,19(6):617-620. |
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