[Ni(C6H4N2)(CHC6H4O)2]配合物晶体结构及性质(英文) |
Crystal Structure and Some Properties of 1,2-N,N-Disallicydene-Phenylamineato Nickel(Ⅱ) Complex |
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摘要: |
关键词: 镍配合物 水杨醛 邻苯二胺 晶体结构 席夫碱 |
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Abstract: The complex has been synthesized and characterized by spectroscopic techniques and single-crystal X-ray analysis. The crystal is orthorhombic , space group P212121 with a=1.6620(3)nm, b=1.7300(4)nm, c=0.5450(1)nm and Z=4. In the crystal lattice, the molecules create a two-dimensional network structure through hydrogen bonds. The C-H…O intermolecular hydrogen bonds connect the title complex to form layer super-molecular plane structure perpendicular to the axis b, with the layers stacked by the Van der Waals interaction. CCDC: 195309. |
Keywords: nickel(Ⅱ) complex salicylaldehyde o-phenylenediamine crystal structure Schiff base |
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王军,卑凤利,马卫兴,杨绪杰,陆路德,汪信.[Ni(C6H4N2)(CHC6H4O)2]配合物晶体结构及性质(英文)[J].无机化学学报,2003,19(6):609-612. |
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