| 牛磺酸合铜螯合物的合成及晶体结构 |
| Synthesis and Crystal Structure of Chelate Complex containing Cu(Ⅱ) and Taurine |
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| 摘要: |
| 关键词: 铜配合物 牛磺酸 晶体结构 螯合物 |
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| Abstract: The new chelate complex formulated [Cu(NC2H6SO3)(phen)(CH3CO2)]·2H2O (phen is o-phenanthroline) has been synthesized and the crystal structure was determined by X-ray diffraction. The crystal structure of the complex belongs to triclinic system with space group and unite cell parameters： a=7.298(1)?， b=11.573(2)?， c=11.942(3)?;α=69.77(1)°， β=80.05(1)°， γ=76.39(1)°， V=915.2(3)?3， Z=2， F(000)=478. Dc=1.680g·cm-3， μ=1.354mm-1， S=1.045. In the crystal structure Cu(Ⅱ) ion is five-coordinated to form a distorted tragonal cone. CCDC： 193112. |
| Keywords: copper complex taurine crystal structure chelate complex |
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| 钟凡,蒋毅民,张淑华.牛磺酸合铜螯合物的合成及晶体结构[J].无机化学学报,2003,19(6):599-602. |
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