| 混配化合物M(α-AP)2(OAc)2(M=Ni、Zn)的室温固相合成及表征 |
| Solid Phase Synthesis at Room Temperature and Characterization of Mixed Coordination Compounds M(α-AP)2(OAc)2 (M=Ni，Zn) |
|
| 摘要: |
| 关键词: 混配化合物 室温固相反应 表征 晶体结构 |
| 基金项目: |
| Abstract: Mixed coordination compounds M(α-AP)2(OAc)2 (M=Ni， Zn) were synthesized individually via solid phase reactions between α-aminopyridine and nickel acetate or zinc acetate at room temperature and were characterized by elemental analysis， IR and X-ray powder diffraction. Zn(α-AP)2(OAc)2 was also determined by 1H NMR， TGA and X-ray single crystal diffraction. The crystal belongs to monoclinic system with space group P21/c， a=9.1900(18)?， b=13.900(3)?， c=13.310(3)?， β=92.40(3)°， V=1698.7(6)?3， Dc=1.453g·cm-3， Z=4， F(000)=768， μ=1.469mm-1， R1=0.0376， wR2=0.1202[I >2σ(I)]. Each zinc(Ⅱ) atom lies at the center of a distorted tetrahedron composed of two oxygen atoms from a pair of monodentate acetate groups and two nitrogen atoms from a pair of pyridine rings. |
| Keywords: mixed coordination compound solid phase reaction at room temperature characterization crystal structure |
| |
| 摘要点击次数: 1208 |
| 全文下载次数: 1674 |
| 李人宇,卑凤利,杨绪杰,许兴友,陆路德,汪信.混配化合物M(α-AP)2(OAc)2(M=Ni、Zn)的室温固相合成及表征[J].无机化学学报,2003,19(5):543-546. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
