固相反应法合成掺铝的α型氢氧化镍及其电化学性能
Solid State Synthesis and Electrochemical Performances of α-Ni(OH)2 including 20% Al
作者单位
许娟 南京师范大学化学与环境科学学院南京 210097 
周益明 南京师范大学化学与环境科学学院南京 210097 
唐亚文 南京师范大学化学与环境科学学院南京 210097 
王青 南京师范大学化学与环境科学学院南京 210097 
陆天虹 南京师范大学化学与环境科学学院南京 210097 
唐琛明 江苏海四达集团有限公司启东 226200 
高效岳 江苏海四达集团有限公司启东 226200 
沈涛 江苏海四达集团有限公司启东 226200 
忻新泉 南京大学配位化学研究所配位化学国家重点实验室南京 210093 
摘要: 
关键词: α-Ni(OH)2 固相合成 镍电极 电化学
基金项目: 
Abstract: Ni(OH)2 including 20% Al was synthesized by solid-state reaction. The result of XRD indicated that the sample thus prepared was α-Ni(OH)2, and its size and crystalline form were much poorer than those of the sample prepared by solution-state reaction. TG and DTA curves showed that α-Ni(OH)2 began to decompose at higher temperature than β-Ni(OH)2. The electrochemical behaviors of the sample were studied by cyclic voltammetry and constant current charge-discharge experiment. It was found that the sample by solid-state reaction had more ex-cellent electrode reversibility, higher discharge potential and higher discharge capacity.
Keywords: α-Ni(OH)2 solid-state synthesis nickel electrode electrochemistry
 
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许娟,周益明,唐亚文,王青,陆天虹,唐琛明,高效岳,沈涛,忻新泉.固相反应法合成掺铝的α型氢氧化镍及其电化学性能[J].无机化学学报,2003,19(5):535-538.
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