| 层状过渡金属硫代亚磷酸盐及其夹层化合物 |
| The Layered Transition Metal Thiophosphates and Their Intercalation Compounds |
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| 摘要: 层状过渡金属硫代亚磷酸盐(MPS3)及其夹层物由于所表现出的特殊的固体物理化学性质而受到关注。本文将主要介绍层状过渡金属硫代亚磷酸盐及其夹层物的合成、结构及固体物理性质等方面的研究状况及进展。 |
| 关键词: 层状过渡金属硫代亚磷酸盐 夹层化合物 固体物理性质 |
| 基金项目: |
| Abstract: The transition metal thiophosphates are layered compounds with the special solid-state physical and chemical properties. Except the redox intercalation， some MPS3(M = Mn， Fe， Cd etc.) exhibited a unique non-redox intercalation based on the cation-exchange route. After intercalation many intercalation compounds based on MPS3 showed some novel physical properties such as ferrimagnetic， photomagnetic and nonlinear optical properties com-pared to the parent compounds， which makes them be the promising magnetic and photo-electronic functional or even multifunctional materials. In this article， the synthesis， structures and solid-state physical properties of the layered transition metal thiophosphates and their intercalation compounds have been reviewed. |
| Keywords: the layered transition metal thiophosphate intercalation compound solid-state physical properties |
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| 陈兴国,张萱,杨楚罗,秦金贵.层状过渡金属硫代亚磷酸盐及其夹层化合物[J].无机化学学报,2003,19(5):449-458. |
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