| Schiff碱双核Mn配合物的合成、结构和性能研究 |
| Synthesis， Structure and Properties of Binuclear Manganese Complexes with Schiff Base Ligands |
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| 摘要: |
| 关键词: Schiff碱 Mn配合物 双核 磁性质 |
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| Abstract: Five manganese complexes of Schiff base were synthesized： [MnⅣ，Ⅳ(μ-O)(Salen)]2·DMF·H2O (1)， [MnⅣ，Ⅳ(μ-O)(5-BrSalen)]2·DMF·0.5H2O (2)， {MnⅣ，Ⅳ(μ-O)[Sal(1，2-pn)]}2·H2O (3)， {MnⅣ，Ⅳ(μ-O)[5-Br-Sal(1，2-pn)]}2·H2O (4)， {MnⅣ，Ⅳ(μ-O)[5-CH3-Sal(1，2-pn)]}2·2H2O (5)， and were characterized by element analysis， IR and UV-Vis spectra. The results of cyclic voltammogram show that Schiff base ligands can drop the potential of manganese and steady high oxide state of manganese. The magnetic properties of 1 and 3 have also been studied. The results show that there is a weak ferromagnetically coupling of MnⅣ2 pair at room and low temperature， and the interactions of complex 3 are weaker than complex 1. |
| Keywords: Schiff base manganese complex binuclear complex magnetic properties |
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| 李珺,吴爱芝,任颜卫,张逢星,史启祯.Schiff碱双核Mn配合物的合成、结构和性能研究[J].无机化学学报,2003,19(3):307-311. |
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