| 氰基桥联双核镝(Ⅲ)-铁(Ⅲ)配合物[DyFe(CN)6(DMF)4(H2O)3]·1.25H2O的合成与结构表征(英文) | |
| Synthesis and Structural Characterization of a Cyano-bridged Dinuclear Dysprosium(Ⅲ)-Iron(Ⅲ) Complex [DyFe(CN)6(DMF)4(H2O)3]·1.25H2O | |
| 摘要: | |
| 关键词: 晶体结构 氰基桥联 双核Dy-Fe配合物 | |
| 基金项目: | |
| Abstract: A dinuclear complex [DyFe(CN)6(DMF)4(H2O)3]·1.25H2O(DMF=N， N-dimethylformamide) 1 based on the cyanide as linkage was prepared and structurally characterized by X-ray single-crystal structure analysis. The Dy(Ⅲ) ion is eight coordinations in a square-antiprism arrangement and the Fe(Ⅲ) ion is six coordinations oriented octahedrally. The neutral units [DyFe(CN)6(DMF)4(H2O)3] are held together by hydrogen bonds formed by lattice water molecules， coordinated water molecules and nitrogen atoms of cyanide coming from other distinct complex units to afford a three-dimensional framework. CCDC： 192314. | |
| Keywords: crystal structure cyano-bridged dinuclear Dy(Ⅲ)-Fe(Ⅲ) complex | |
| 摘要点击次数: 1409 | |
| 全文下载次数: 1637 | |
| 李建荣,蔡丽珍,郑艳,郭国聪,卜显和,黄锦顺.氰基桥联双核镝(Ⅲ)-铁(Ⅲ)配合物[DyFe(CN)6(DMF)4(H2O)3]·1.25H2O的合成与结构表征(英文)[J].无机化学学报,2003,19(1):91-94. | |
| 查看全文 查看/发表评论 下载PDF阅读器 | |
| Support information: | |
|
| |
|
| |
|
| |