| 一种二帽pseudo-Keggin结构簇合物[HN(C2H5)3]3[N(C2H5)3]2[MoⅣ8MoⅤ4VⅣ2O38(PO4)]的水热合成、结构和性质研究 |
| Hydrothermal Synthesis， Crystal Structure and Properties of the Cluster Compound with a Bi-capped pseudo-Keggin Structure： [HN(C2H5)3]3[N(C2H5)3]2[MoⅣ8 |
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| 摘要: |
| 关键词: 金属氧簇 二帽pseudo-Keggin结构 水热合成 晶体结构 |
| 基金项目: |
| Abstract: The novel polyoxometalate， [HN(C2H5)3]3[N(C2H5)3]2[MoⅣ8MoⅤ4VⅣ2O38(PO4)]， was synthesized and characterized by elementary analysis， EPR， IR spectra and X-ray diffraction. The compound crystallizes in triclinic system， space group P1 with a= 1.41999(2)nm， b=1.43467(2)nm， c=1.694610(10)nm， α=95.7250(10)°， β=92.2110(10)°， γ=92.6060(10)°， V=3.42829(7)nm3， Z=2， Dc=2.388g·cm-3， Mr=2465.10g·mol-1， μ=2.489mm-1， F(000)=2388， R1=0.0584， wR2=0.1461， S=1.164. The het-eropolyanion is a bi-capped pseudo-Keggin complex. CCDC： 186645. |
| Keywords: polyoxometalate bi-capped pseudo-Keggin structure hydrothermal synthesis crystal structure |
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| 崔小兵,林之恩,杨国昱.一种二帽pseudo-Keggin结构簇合物[HN(C2H5)3]3[N(C2H5)3]2[MoⅣ8MoⅤ4VⅣ2O38(PO4)]的水热合成、结构和性质研究[J].无机化学学报,2003,19(1):86-90. |
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