| 配位聚合物的三阶非线性光学性质 |
| Third-Order Nonlinear Optical Properties of the Coordination Polymers |
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| 摘要: 本文概括了配位聚合物的三阶非线性光学性质，并总结了其结构与三阶非线性光学性质之间的关系。对于一维结构的配位聚合物，因配体不同或者中心金属离子的价层电子构型不同可呈现自聚焦或自散焦效应;二维结构配位聚合物的三阶非线性光学性质则与配体和中心金属离子无关，均呈现自聚焦效应;三维结构配位聚合物的自聚焦或自散焦效应主要受中心金属离子价层电子构型的影响。 |
| 关键词: 配位聚合物 三阶非线性光学性质 自散焦 自聚焦 Z-扫描 |
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| Abstract: In this paper， we review the third-order NLO properties of coordination polymers， and summarize the rela-tionship between the crystal structures and the third-order NLO properties. One-dimensional coordination polymers exhibit either self-defocusing or self-focusing effects depending on the ligands and the valence shell structures of the central ions; All the two-dimensional coordination polymers show strong self-focusing effects regardless of the central ions and ligands; Three-dimensional coordination polymers show self-defocusing or self-focusing effects depending on the valence shell structures of the central ions. |
| Keywords: coordination polymer third-order nonlinear optical property self-defocusing effect self-focusing effect Z-scan |
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| 孟祥茹,赵金安,侯红卫,米立伟.配位聚合物的三阶非线性光学性质[J].无机化学学报,2003,19(1):15-19. |
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