| 镧-锌杂多核配合物的合成和晶体结构(英文) | |||||||||
| Synthesis and Crystal Structure of Heteronuclear La(Ⅲ)-Zn(Ⅱ) Complex | |||||||||
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| 关键词: 镧 锌 杂多核 晶体结构 | |||||||||
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| Abstract: A new heteronuclear complex, [LaZnL5(C2H5OH)(phen)]2 (HL=α-methylacrylic acid, phen=1, 10-phen- anthroline), was synthesized and characterized by elemental analysis, infrared absorption spectra (IR) and single crystal X-ray diffraction analysis. The complex crystallizes in space group P1 with the cell dimensions a=12.614(3), b=14.485(4), c=12.148(2)?, α=109.68(2), β=115.65(1), γ=66.87(2)°. The complex mole- cule is a discrete tetranuclear molecule bridging by α-methylacrylate groups. | |||||||||
| Keywords: lanthanum zinc heteronuclear crystal structure | |||||||||
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| 吴斌,陆维敏,郑小明.镧-锌杂多核配合物的合成和晶体结构(英文)[J].无机化学学报,2002,18(10):1045-1048. | |||||||||
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