| 过渡金属-碱土金属铜镁异双核配合物的合成、晶体结构和性质研究 |
| Synthesis, Molecular Structure and Properties of Heterometal Binuclear Complex, [CuMg(TS)(H2O)]·H2O |
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| 摘要: |
| 关键词: 铜 镁 异双核配合物 热性质 EPR |
| 基金项目: |
| Abstract: The transition metal and alkaline earth metal heterobinuclear complex[CuMg(TS)(H2O)·H2O],where TS is the schiff base N,N′-bis(3-carboxylsalidene)trimethylenediamine, was synthesised and its crystal structure was determined by the single-crystal X-ray diffraction method at room temperature. It crystallizes in the monoclinic system, space group P21/n. The lattice parameters are a=12.041(2)?, b=14.736(3)?, c=12.062(2)?, β=118.00(3)°, Z=4 with R1=0.0364. The thermal property and EPR studies of the complex according to crystal structure are also investigated. CCDC: 182408. |
| Keywords: copper magnesium heterobinuclear complex thermal property EPR |
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| 陶偌偈,臧双全,于兆文.过渡金属-碱土金属铜镁异双核配合物的合成、晶体结构和性质研究[J].无机化学学报,2002,18(9):907-910. |
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