配合物[Mn(C13H8N2OBr)2(C5H5N)2]·3C5H5N的结构与磁性研究 |
Study on Crystal Structure and Magnetic Susceptibility of [Mn(C13H8N2OBr)2(C5H5N)2]·3C5H5N |
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摘要: |
关键词: 锰配合物 Schiff碱 晶体结构 合成 磁性能 |
基金项目: |
Abstract: The complex [Mn(C13H8N2OBr)2(C5H5N)2]·3C5H5N has been synthesized and characterized by X-Ray diffraction, IR and variable temperature (~10 to ~278K) magnetic susceptibility. X-Ray diffraction result for the single crystal shows that the crystal belongs to monoclinic, space group P21/c, a=1.0969(3)nm, b=2.0903(5)nm, c=2.0481(6)nm, β=97.366(6), V=4.657(2)nm3, Z=4, Dc=1.47g·cm-3。 |
Keywords: manganese complex Schiff base crystal structure synthesis magnetic properties |
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李君,张逢星,史启祯.配合物[Mn(C13H8N2OBr)2(C5H5N)2]·3C5H5N的结构与磁性研究[J].无机化学学报,2002,18(6):643-645. |
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