| Abstract: A new complex with mixed-quadriligand [Ce(CH2=C(CH3)-COO)2(NO3)(phen)]2 has been synthesized in aqueous solution of slight acidity and characterized by elementary analysis, IR and TGA. The crystal structure determination shows that the complex belongs to triclinic, space group P1, a=9.614?, b=10.047?, c=11.821?, Z=2, α=100.88(3)°, β=106.29(3)°, γ=97.93(2)°, V=1054(5)?3, Dc=1.741g·cm-3, F(000)=546.00, μ(MoKα)=22.06cm-1. And the crystal is consisted of a binuclear molecule. The coordina-tion of Ce3+ is nine. |
