| 过渡金属一取代Keggin结构钼磷酸盐掺杂的聚吡咯的制备、表征与导电性研究 |
| Preparation, Characterization and Conductivity of Polypyrrole Doped with the Transition Metal Substituted Phosphomolybdates with Keggin Structure |
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| 摘要: |
| 关键词: 聚吡咯 掺杂 多金属氧酸盐 导电性 |
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| Abstract: Five hybrid organic-inorganic materials have been prepared with pyrrole and the transition metal substituted Keggin structure phosphomolybdate anions ([PMo11ZO39]5-, Z=Mn,Co,Ni,Cu,Zn) by chemical polymerization. The phosphomolybdates are anchored within the polymer matrix and reduced to mixedvalence phosphomolybdates. The materials are characterized by elemental analysis, IR spectra, thermogravimetric analysis, X-ray photoelectron spectroscopy and electron spin resonance. Conductivity measurement indicates that the title materials have good conductivity. |
| Keywords: polypyrrole dope polyoxometallate conductivity |
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| 樊莹,柳士忠.过渡金属一取代Keggin结构钼磷酸盐掺杂的聚吡咯的制备、表征与导电性研究[J].无机化学学报,2002,18(6):635-638. |
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