| 三维超分子[Ni(hmt)2(SCN)2(H2O)2][Ni(SCN)2(H2O)4](H2O)2的自组装,晶体结构及磁性质(hmt=六次甲基四胺)(英文) |
| Self-Assembly,Crystal Structure and Magnetic Properties of Three-Dimensional Supramolecular Complex [Ni(hmt)2(SCN)2(H2O)2][Ni(SCN)2(H2O)4](H2O)2(hmt=hexamet |
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| 关键词: 自组装 超分子配合物 氢键 磁性 |
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| Abstract: Compound [Ni(hmt)2(SCN)2(H2O)2][Ni(SCN)2(H2O)4](H2O)2 (hmt=hexamethylenetetramine) was pre-pared and structurally characterized by means of X-ray single crystal diffraction. The two neutral units [Ni(hmt)2(SCN)2(H2O)2] and [Ni(SCN)2(H2O)4] are joined together through hydrogen bonds N…H-O, O…H-O and S…H-O. In the solid state, the compound has three-dimensional network structure. The determination of its variable-temperature magnetic susceptibilities (5～300K) shows that the magnetic behavior obeys the Curie-Weiss law over the whole temperature ranges. |
| Keywords: self-assembly supramolecular complex hydrogen bonds magnetic properties |
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| 李纲,朱玉,李林科,侯红卫,樊耀亭,杜晨霞.三维超分子[Ni(hmt)2(SCN)2(H2O)2][Ni(SCN)2(H2O)4](H2O)2的自组装,晶体结构及磁性质(hmt=六次甲基四胺)(英文)[J].无机化学学报,2002,18(5):537-540. |
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