| 配位化学中的C-H…π非键弱相互作用 |
| C-H…π Interaction in Coordination Chemistry |
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| 摘要: 随着超分子化学研究的深入和发展,C-H…π非键弱相互作用越来越多地在晶体工程学、分子识别、主客体化学、自组装超分子体系以及生物大分子与配体相互作用等领域中被关注。本文综述了在配位化学中的C-H…π非键弱相互作用,它不仅存在于配合物分子内,亦可在配合物分子间观察到,并对利用配合物体系进行C-H…π非键弱相互作用体系研究提出一些设想。 |
| 关键词: 配合物 分子内C-H…π相互作用 分子间C-H…π相互作用 |
| 基金项目: |
| Abstract: As a consequence of progress of supramolecular chemistry, C-H…π interaction in crystal engineering, molecular recognition, host-guest chemistry, supramolecular assemblies, protein-ligand interactions has been con-siderable interest in recent years. In this paper, the C-H…π interaction was briefly introduced, and the in-tramolecular or intermolecular C-H…π interaction in coordination chemistry were summarized. Thus, the com-plex systems offer a medium to study the C-H…π interaction. |
| Keywords: complexes intramolecular C-H…π interaction intermolecular C-H…π interaction |
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| 摘要点击次数: 1782 |
| 全文下载次数: 2009 |
| 郭辉瑞,陶朱,祝黔江,薛赛凤.配位化学中的C-H…π非键弱相互作用[J].无机化学学报,2002,18(5):435-441. |
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