| 四-邻苯二甲酰亚胺甲基酞菁锌的两种合成方法比较 |
| Compare Two Methods for Synthesis of Phthalimidomethyl Phthalocyanine Zinc |
| 作者 | 单位 | | 彭亦如 | 福州大学功能材料研究所,化学化工学院,福州 350002
福建师范大学化学系,福州 350007
中国科学院福建物质结构研究所国家重点实验室,福州 350002 | | 林志鹏 | 福州大学功能材料研究所,化学化工学院,福州 350002
中国科学院福建物质结构研究所国家重点实验室,福州 350002 | | 薛金萍 | 福州大学功能材料研究所,化学化工学院,福州 350002
中国科学院福建物质结构研究所国家重点实验室,福州 350002 | | 陈耐生 | 福州大学功能材料研究所,化学化工学院,福州 350002
中国科学院福建物质结构研究所国家重点实验室,福州 350002 | | 黄金陵 | 福州大学功能材料研究所,化学化工学院,福州 350002
中国科学院福建物质结构研究所国家重点实验室,福州 350002 |
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| 摘要: |
| 关键词: 酞菁锌配合物 合成方法 表征 |
| 基金项目: |
| Abstract: Molecular precursors phthalimidomethyl phthalic acid and phthalimidomethyl phthalonitrile were synthesized for the first time and both were able to condensation to form tetra-phthalimidomethyl phthalocyanine zinc through “ammomium molybdate method” and “DBU method ”respectively. The precursors and title compounds were char-acterized by element analysis, IR, UV/Vis as well as NMR. The two synthesis methods were compared, the result indicated that using the phthalimidomethyl phthalic acid as precursor through the former method, the product was an isomer with C4h symmetry, while using phthalimidomethyl phthalonitrile as precursor through the latter method, the products were a mixture of different isomers. |
| Keywords: phthalocyanine zinc synthesis method characterization |
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| 彭亦如,林志鹏,薛金萍,陈耐生,黄金陵.四-邻苯二甲酰亚胺甲基酞菁锌的两种合成方法比较[J].无机化学学报,2002,18(3):321-324. |
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