| [Pb2(TNR)(NO3)2(H2O)]的制备和晶体结构研究 |
| Preparation and Molecular Structure of [Pb2(TNR)(NO3)2(H2O)] |
|
| 摘要: |
| 关键词: 铅配合物 制备 晶体结构 |
| 基金项目: |
| Abstract: [Pb2(TNR)(NO3)2(H2O)] was prepared by reaction of the aqueous solution of lead nitrate and magnesium styphnate. The crystal structure of Pb2(TNR)(NO3)2(H2O)was determined by single crystal diffraction analysis. The crystal is triclinic, space group P1 with crystal parameters a=0.7279(2)nm,b=1.0698(2)nm,c=1.0738(2)nm;α=86.82(1)°,β=89.52(2)°,γ=83.50(2)°;V=0.8295(3)nm3,Z=2,Dc=3.201g·cm-3, F(000)=716. The final R value is 0.0358.In the crystal structure, one lead ion was represented by nine coor-dination geometry; the other was showed as ten coordination geometry. |
| Keywords: lead complex preparation crystal structure |
| |
| 摘要点击次数: 1433 |
| 全文下载次数: 1812 |
| 张同来,杨永明,张建国,邵兵,杨利,郁开北.[Pb2(TNR)(NO3)2(H2O)]的制备和晶体结构研究[J].无机化学学报,2002,18(3):305-308. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
