| 配合物[Mn(bipy)3](ClO4)2的晶体结构和热分析研究 |
| Crysyal Structure and Thermal Analysis of [Mn(bipy)3](ClO4)2 |
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| 摘要: |
| 关键词: 锰(Ⅱ)配合物 联吡啶 晶体结构 热分析 热分解动力学 |
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| Abstract: The complex [Mn(bipy)3]·(ClO4)2 was synthesied and characterized by X-ray diffraction. X-ray diffraction result for the single crystal showed that the crystal belongs to triclinic, space group P1, a=0.8123(2),b=1.1024(2), c=1.8646(4)nm,α=102.30(3)°,β=91.00(3)°,γ=99.69(3)°,V=1.6056(6)nm3,Z=2,Dc=1.494g·cm-3. The thermal decomposition of [Mn(bipy)3](ClO4)2 occurred in a three steps pattern. The reaction mechanism of the first step decomposition was deduced as n(1-α)[-ln(1-α)](n-1)/n with the activation energy of 130kJ·mol-1. |
| Keywords: manganese(Ⅱ)complex bipyridine crystal structure thermal analysis thermal decomposition kinetics |
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| 李君,张逢星,史启祯.配合物[Mn(bipy)3](ClO4)2的晶体结构和热分析研究[J].无机化学学报,2002,18(3):289-293. |
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