| [Cu(TO)2(H2O)4](PA)2的合成和晶体结构 |
| Preparation and Crystal Structure of [Cu(TO)2(H2O)4](PA)2 |
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| 摘要: |
| 关键词: 制备 1,2,4-三唑-5-酮 铜配合物 晶体结构 |
| 基金项目: |
| Abstract: [Cu(TO)2(H2O)4](PA)2 was prepared by mixing the aqueous solution of 1,2,4-triazol-5-one(TO) and Cu(PA)2. The molecular structure and crystal structure of the title complex was determined by X-ray single crystal diffraction method. The crystal is triclinic, space group with a=0.7321(1)nm,b=0.7474(2)nm,c=1.3649(3)nm;α=88.65(2)°,β=85.63(1)°,γ=63.35(1)°;V=0.6655(2)nm3,Z=1. The Cu2+ coordinated with two TO molecule through its 2-nitrogen atom and four water molecules and showed an octahedral configuration. |
| Keywords: preparation 1,2,4-triazol-5-one(TO) copper complex crystal structure |
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| 张建国,张同来,杨利,毛利秋,郁开北.[Cu(TO)2(H2O)4](PA)2的合成和晶体结构[J].无机化学学报,2002,18(3):284-288. |
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