| 配合物型非线性光学材料的晶体工程 |
| Crystal Engineering of Nonlinear Optical Materials based on Coordination Complexes |
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| 摘要: |
| 关键词: 拓扑结构 晶体工程 非线性光学材料 超分子 |
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| Abstract: Coordination complexes derived thiosemicarbazone ligands were designed to exhibit the potential factors to influence the molecular packing. The aromatic group 4,5-diazafluorene can form strong hydrogen bonds with the lattice water molecules from which connect the molecules aggregating into a one-dimensional screw chain. It seems that the existence of those hydrogen bonds is essential for the molecules crystallized in noncentral space group and exhibiting obviously SHG efficiency. |
| Keywords: topolography crystal engineering non-linear optical property supramolecule |
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| 摘要点击次数: 2344 |
| 全文下载次数: 2025 |
| 刘泽华,何成,房晨婕,段春迎.配合物型非线性光学材料的晶体工程[J].无机化学学报,2002,18(1):112-114. |
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