| 手性配合物模板剂对磷酸锌骨架的手性传递 |
| Chiral Transference from the Chiral Metal Complex to the Zinc Phosphates |
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| 摘要: 以外消旋的钴胺配合物Co(en)3Cl3为模板剂,在水热体系中合成出二种新颖的磷酸锌化合物:[Co(en)3]·[Zn8P6O24Cl]·2H2O(1)和[Co(en)3]2·[Zn6P8O32H8](2 |
| 关键词: 磷酸锌 金属配合物 水热合成 结构 手性 |
| 基金项目: |
| Abstract: Using a racemic mixture of chiral metal complex Co(en)3Cl3 as a template, two novel zinc phosphates [Co(en)3]·[Zn8P6O24Cl]·2H2O(1) and [Co(en)3]2·[Zn6P8O32H8](2) have been prepared hydrothermally. Single-crystal structureal analysis demonstrates that both compounds contain chiral inorganic structural motifs and that the enantiomers of the chiral complex are separated orderly as Δ and Λ configurations in the inorganic host. This work studies the chiral transference from the chiral metal complex to the inorganic framework. |
| Keywords: zinc phosphates metal complex hydrothermal synthesis structures chiral |
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| 于吉红,王宇,施展,徐如人.手性配合物模板剂对磷酸锌骨架的手性传递[J].无机化学学报,2002,18(1):51-55. |
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